Engine detonation has nothing to do with an engine being tough. It has to do with whether the air/fuel mixture is so lean that the mixture heats up so much under compression, that the mixture explodes before it is supposed to, damaging the pistons.
Hey Cheers, if you have a Superchips modified ECU, then yes, nos will probably damage your car. What superchips mods due to our cars, is advance the timing, which is why you need high-octane gasoline--It prevents detonation, because higher octane gas is more resistant to ignition. Thats why race car engines backfire a lot, anyways.... With your timing advanced, you need higher octane gas to keep it from detonating, so adding NOS will cause a leaner air/fuel mixture, and will lead to detonation. If the shot of NOS is small enough, that your stock fuel pump can support it, then you will be ok. If your fuel pump cannot handle it, you will be needing some new pistons!!! Again, a small shot of NOS (no idea how much) would probably be ok, but you would have to ensure that you don't get a lean mixture and therefore detonation by measuring the temperature of the exhaust gasses.
If you need to know anything else, just ask...